Haas, Rainer; Schmidt, Torsten Claus; Steinbach, Klaus; von Löw, Eberhard:
Chromatographic determination of phenylarsenic compounds
In: Fresenius' Journal of Analytical Chemistry, Jg. 361 (1998), Heft 3, S. 313 - 318
1998Artikel/Aufsatz in Zeitschrift
Chemie
Titel:
Chromatographic determination of phenylarsenic compounds
Autor(in):
Haas, Rainer; Schmidt, Torsten ClausLSF; Steinbach, Klaus; von Löw, Eberhard
Erscheinungsjahr
1998

Abstract:

Gas chromatographic (GC) and liquid chromatographic methods for the investigation of phenylarsenic compounds are presented. With gas chromatography using an electron capture detector (ECD), the chemical warfare agents PFIFFIKUS, CLARK I and CLARK II can be detected. After derivatization with mercaptans and dimercaptans the sum of diphenylarsenic compounds resp. phenylarsenic and phenylarsonic compounds can be detected as the mercapto reap. dimercapto derivatives. High performance liquid chromatography (HPLC) analysis may be used for the detection of triphenylarsenic compounds and ADAMSITE.