The T-geometry of O-H...O and C-H...O hydrogen bonding groups in the title mol. (5-NSA) form a brick wall network that is modularly expanded and transformed to chair cyclohexane and honeycomb architectures in mol. complexes with trans-1,4-dithiane-1,4-dioxide and dioxane. The variation in hydrogen bond synthons results in different examples of topol. related (6,3) nets.