Boese, Roland; Blaeser, Dieter; Gomann, Klaus; Brinker, Udo H.:
Spiropentane as a tensile spring
In: Journal of the American Chemical Society : JACS, Vol. 111 (1989), No. 4, pp. 1501 - 1503
1989article/chapter in journalOpen Access
Chemistry
Related: 1 publication(s)
Title in English:
Spiropentane as a tensile spring
Author:
Boese, RolandUDE
LSF ID
10873
Other
connected with university
;
Blaeser, Dieter;Gomann, Klaus;Brinker, Udo H.
Year of publication:
1989
Open Access?:
Open Access
Language of text:
English

Abstract:

X-ray analyses of spiropentane (I) and its bridged analogs II and III showed that several bond lengths differed from their calcd. values. The bending of the spiropentane unit in III is greater than in II, whereas the torsion is released.