Schulz, Stephan; Gutschank, Benjamin; Bläser, Dieter; Boese, Roland; Wölper, Christoph:
Synthesis, Structure and Reactivity of a Tetranuclear Amidinato Zinc Hydride Complex
In: Organometallics, Vol. 29 (2010), p. 6133
2010article/chapter in journalOA Green
ChemistryFaculty of Chemistry » Anorganische Chemie
Related: 1 publication(s)
Title in English:
Synthesis, Structure and Reactivity of a Tetranuclear Amidinato Zinc Hydride Complex
Author:
Schulz, StephanUDE
GND
1135302499
GND
1205420940
LSF ID
49379
ORCID
0000-0003-2896-4488ORCID iD
Other
connected with university
;Gutschank, Benjamin;Bläser, Dieter;Boese, RolandUDE
LSF ID
10873
Other
connected with university
;Wölper, Christoph
Year of publication:
2010
Open Access?:
OA Green
DOI
10.1021/om100966d
DuEPublico 2 ID
duepublico_mods_00073232
URN
urn:nbn:de:hbz:464-20201104-101948-8
Language of text:
English
Appears in
Organometallics
Place of publication:
Washington
Publisher:
American Chemical Society (ACS)
in:
Vol. 29 (2010), p. 6133
ISSN
1520-6041 Show availability online & print
ISSN
0276-7333 Show availability online & print
ZDB ID
2006302-7
Library shelfmark:
70 Z 240

Abstract in English:

The tetranuclear amidinato zinc hydride complex {C[C(Ni-Pr)2ZnH]4} (3) was synthesized by reaction of the Cl-substituted complex {C[C(Ni-Pr)2ZnCl]4} with CaH2. 3 was found to react with phenylacetylene and acetylene at ambient temperature with elimination of H2 and subsequent formation of C[C(Ni-Pr)2ZnC≡CPh]4 (4) and {C[C(Ni-Pr)2ZnC≡CH]4 (5), respectively. 3−5 have been characterized by multinuclear NMR (1H, 13C) and IR spectroscopy, elemental analyses, and single-crystal X-ray diffraction.