Synthesis and Structural Characterization of New Zinc Amidinate Complexes
In: Organometallics, Vol. 29 (2010), p. 6097
2010article/chapter in journalOA Green
ChemistryFaculty of Chemistry » Anorganische Chemie
Related: 1 publication(s)
Title in English:
Synthesis and Structural Characterization of New Zinc Amidinate Complexes
Author:
Schulz, StephanUDE
- GND
- 1135302499
- GND
- 1205420940
- LSF ID
- 49379
- ORCID
-
0000-0003-2896-4488
- Other
- connected with university
- LSF ID
- 51250
- Other
- connected with university
- LSF ID
- 10873
- Other
- connected with university
Year of publication:
2010
Open Access?:
OA Green
DuEPublico 2 ID
Appears in
Place of publication:
Washington
Publisher:
American Chemical Society (ACS)
in:
Vol. 29 (2010), p. 6097
ISSN
ISSN
ZDB ID
Library shelfmark:
Abstract in English:
The synthesis and reactivity of heteroleptic zinc complexes of the type LZnX (X = Me, I) containing amidinate ligands L of varying steric bulk were investigated. Complexes of the type LZnMe, which were obtained from the homoleptic complexes L2Zn upon reaction with ZnMe2, react with iodine with subsequent formation of LZnI. Single-crystal X-ray structures of the amidinate zinc complexes [{MeC(Ni-Pr)2}ZnMe]2, 1, [{MeC(Ni-Pr)2}ZnI]2LiI(OEt)2, 3, [t-BuC(NDipp)2]ZnMe, 5, [t-BuC(NDipp)2]ZnMe(t-BuPy), 6, [{t-BuC(NDipp)2}Zn(μ-I)]2, 7, and [t-BuC{N(H)Dipp}2][Al{OC(CF3)3}4], 8, are reported.