Schulz, Stephan; Schmidt, Sarah; Bläser, Dieter; Boese, Roland; Bolte, Michael:
Synthesis and Structural Characterization of New Zinc Amidinate Complexes
In: Organometallics, Band 29 (2010), S. 6097
2010Artikel/Aufsatz in ZeitschriftOA Grün
ChemieFakultät für Chemie » Anorganische Chemie
Damit verbunden: 1 Publikation(en)
Titel in Englisch:
Synthesis and Structural Characterization of New Zinc Amidinate Complexes
Autor*in:
Schulz, StephanUDE
GND
1135302499
GND
1205420940
LSF ID
49379
ORCID
0000-0003-2896-4488ORCID iD
Sonstiges
der Hochschule zugeordnete*r Autor*in
;
Schmidt, SarahUDE
LSF ID
51250
Sonstiges
der Hochschule zugeordnete*r Autor*in
;
Bläser, Dieter;Boese, RolandUDE
LSF ID
10873
Sonstiges
der Hochschule zugeordnete*r Autor*in
;
Bolte, Michael
Erscheinungsjahr:
2010
Open Access?:
OA Grün
DuEPublico 2 ID

Abstract in Englisch:

The synthesis and reactivity of heteroleptic zinc complexes of the type LZnX (X = Me, I) containing amidinate ligands L of varying steric bulk were investigated. Complexes of the type LZnMe, which were obtained from the homoleptic complexes L2Zn upon reaction with ZnMe2, react with iodine with subsequent formation of LZnI. Single-crystal X-ray structures of the amidinate zinc complexes [{MeC(Ni-Pr)2}ZnMe]2, 1, [{MeC(Ni-Pr)2}ZnI]2LiI(OEt)2, 3, [t-BuC(NDipp)2]ZnMe, 5, [t-BuC(NDipp)2]ZnMe(t-BuPy), 6, [{t-BuC(NDipp)2}Zn(μ-I)]2, 7, and [t-BuC{N(H)Dipp}2][Al{OC(CF3)3}4], 8, are reported.