Synthesis, Structure and Reactivity of a Tetranuclear Amidinato Zinc Hydride Complex
In: Organometallics, Vol. 29 (2010), p. 6133
2010article/chapter in journalOA Green
ChemistryFaculty of Chemistry » Anorganische Chemie
Related: 1 publication(s)
Title in English:
Synthesis, Structure and Reactivity of a Tetranuclear Amidinato Zinc Hydride Complex
Author:
Schulz, StephanUDE
- GND
- 1135302499
- GND
- 1205420940
- LSF ID
- 49379
- ORCID
- 0000-0003-2896-4488
- Other
- connected with university
- LSF ID
- 10873
- Other
- connected with university
Year of publication:
2010
Open Access?:
OA Green
DuEPublico 2 ID
Language of text:
English
Abstract in English:
The tetranuclear amidinato zinc hydride complex {C[C(Ni-Pr)2ZnH]4} (3) was synthesized by reaction of the Cl-substituted complex {C[C(Ni-Pr)2ZnCl]4} with CaH2. 3 was found to react with phenylacetylene and acetylene at ambient temperature with elimination of H2 and subsequent formation of C[C(Ni-Pr)2ZnC≡CPh]4 (4) and {C[C(Ni-Pr)2ZnC≡CH]4 (5), respectively. 3−5 have been characterized by multinuclear NMR (1H, 13C) and IR spectroscopy, elemental analyses, and single-crystal X-ray diffraction.