Base-stabilized monomeric stibinoalane dmap-Al(Et2)Sb(tBu)2
In: Journal of Chemical Crystallography, Jg. 41 (2011), Heft 3, S. 349 - 352
2011Artikel/Aufsatz in ZeitschriftOA Grün
ChemieFakultät für Chemie » Anorganische Chemie
Damit verbunden: 1 Publikation(en)
Titel:
Base-stabilized monomeric stibinoalane dmap-Al(Et2)Sb(tBu)2
Autor*in:
Schulz, StephanUDE
- GND
- 1135302499
- GND
- 1205420940
- LSF ID
- 49379
- ORCID
- 0000-0003-2896-4488
- Sonstiges
- der Hochschule zugeordnete*r Autor*in
Erscheinungsjahr:
2011
Open Access?:
OA Grün
DuEPublico 2 ID
Sprache des Textes:
Englisch
Abstract in Englisch:
The six-membered heterocycle [Me2AlSb(t-Bu)2]3 was reacted with the strong Lewis-base 4-dimethylaminopyridine (dmap), yielding the first completely alkyl-substituted monomeric complex dmap–Al(Me2)Sb(t-Bu)2 1. 1 was characterized by NMR spectroscopy and single crystal X-ray diffraction. 1 is monoclinic, space group P2 1 /n with a = 9.9004(2) Å, b = 16.8166(3) Å, c = 13.8400(3) Å, β = 100.746(1)° and Z = 4.