Fall-Off Curves for the Reaction ClO + NO2( + N2) ClONO2 (+N2)
In: Zeitschrift für Naturforschung A : Journal of Physical Sciences, Vol. 32 (1977), No. 6, pp. 648 - 651
1977article/chapter in journalOpen Access
ChemistryFaculty of Chemistry » Physikalische Chemie
Related: 1 publication(s)
Title in English:
Fall-Off Curves for the Reaction ClO + NO2( + N2) ClONO2 (+N2)
Author:
Zellner, ReinhardUDE
- GND
- 1014420970
- LSF ID
- 11046
- Other
- connected with university
Year of publication:
1977
Open Access?:
Open Access
Scopus ID
Language of text:
English
Abstract in English:
Fall-off curves for the reaction ClO + NO2(+N2)->ClONO2(+N2) at 300 and 220 K have been calcd. from Kassel integrals by use of a theor. derived high-pressure limit and the exptl. detd. low-pressure limit as ref. points. The reaction deviates considerably from the low-pressure limit at pressures >10 torr. Effective rate consts. for use in atm. models of ClONO2 formation are derived.