X-Ray crystal and ab initio structure of 3-ethynylcyclopropene : a curiously short carbon–carbon double bond
In: Chemical Communications : ChemComm (1998), Heft 10, S. 1137 - 1138
Titel in Englisch:
X-Ray crystal and ab initio structure of 3-ethynylcyclopropene : a curiously short carbon–carbon double bond
Autor*in:
Baldridge, Kim K.;Biggs, Bluegrass;Blaser, Dieter;Boese, RolandUDE
- LSF ID
- 10873
- Sonstiges
- der Hochschule zugeordnete*r Autor*in
korrespondierende*r Autor*in
- Sonstiges
- korrespondierende*r Autor*in
- Sonstiges
- korrespondierende*r Autor*in
Erscheinungsjahr:
1998
Open Access?:
Open Access
DOI
Sprache des Textes:
Englisch
Abstract:
The X-ray crystal structure of 3-ethynylcyclopropene shows that the carbon-carbon double bond of the mol. is unusually short [1.255(2) .ANG.], whereas theor. calcns. suggest a relative insensitivity of the bond length to adjacent orbital interactions.