[Fe(CO)4C(O)NMe2][C(NMe2)3] : The first structure determination on an organometallic compound with the carbenium ion [C(NMe2)3]+
In: Zeitschrift für Naturforschung B, Journal of Chemical Sciences, Vol. 43 (1988), No. 8, pp. 945 - 948
Title in English:
[Fe(CO)4C(O)NMe2][C(NMe2)3] : The first structure determination on an organometallic compound with the carbenium ion [C(NMe2)3]+
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Year of publication:
1988
Open Access?:
Open Access
Place of publication:
Berlin
Publisher:
De Gruyter
in:
Vol. 43 (1988), No. 8, pp. 945 - 948
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Note:
seit 2.1947 -
Abstract:
The crystal structure of the carbamoyl complex [(CO)4FeC(O)NMe2][C(NMe2)3] is described. The cation has a planar CN3 array with sp2 hybridized C and N atoms. The carbamoyl group of the anion occupies an axial position in the trigonal bipyramidal environment of the iron atom.